Estudio cinético de la extracción sólido-líquido de cafeína en Ilex guayusa Loes
Palabras clave:
cinética, ecuación de Peleg, extracto acuoso, modelo matemático
Resumen
El estudio cinético de la extracción sólido-líquido de cafeína en Ilex guayusa Loes aborda una etapa crítica en el aislamiento de alcaloides como la cafeína. La extracción sólido-líquido, una técnica ampliamente utilizada, desempeña un papel fundamental en la obtención de estos compuestos. El estudio tuvo como objetivo evaluar la aplicabilidad de la ecuación de Peleg para modelar la extracción sólido-líquido de cafeína en hojas de Ilex guayusa Loes. El contenido de cafeína se determinó por espectroscopía de absorción UV-visible. La cinética de extracción se estimó utilizando la ecuación de Peleg de dos parámetros. La correspondencia de los resultados experimentales y los predichos por el modelo se estableció mediante el cálculo de correlación de Pearson. Los resultados indicaron efectos significativos de la temperatura y el tiempo de extracción en el contenido de cafeína, con concentraciones que variaron desde 0,24 hasta 1,52 g.100 g-1 a diferentes temperaturas de extracción (30, 40 y 50 °C). La ecuación de Peleg modeló eficazmente la cinética de extracción de cafeína, con altos coeficientes de correlación de Pearson (0,96895 a 0,99685) que confirmaron su idoneidad para predecir la concentración de cafeína. Estos resultados resaltan la importancia de comprender la cinética de extracción para optimizar los procesos de extracción de cafeína, ofreciendo ideas valiosas para las industrias que utilizan extractos de Ilex guayusa Loes.
Descargas
La descarga de datos todavía no está disponible.
Citas
Bitwell, C., Indra, S. Sen, Luke, C., & Kakoma, M. K. (2023). A review of modern and conventional extraction techniques and their applications for extracting phytochemicals from plants. Scientific African, 19, 1–7. Doi.org/10.1016/J.SCIAF.2023.E01585
Bucić-Kojić, A., Planinić, M., Tomas, S., Bilić, M., & Velić, D. (2007). Study of solid-liquid extraction kinetics of total polyphenols from grape seeds. Journal of Food Engineering, 81(1), 236–242. Doi.org/10.1016/j.jfoodeng.2006.10.027
Cadena-Carrera, S., Tramontin, D. P., Jacques, R., Scapin, E., Müller, J. M., & Hense, H. (2023). Green-based methods to obtain bioactive compounds from Ilex guayusa Loes. using polar solvent. Natural Product Research, 37(18), 3103–3108. Doi.org/10.1080/14786419.2022.2140802
Carvalho, S. D., Ortega, M., Orellana, M., Rodríguez, M., Folta, K. M., & Torres, M. de L. (2021). In vitro propagation of the Amazonian medicinal plant guayusa (Ilex guayusa) and effects of light in the growth and development of this shade tolerant plant. Plant Cell, Tissue and Organ Culture, 147(3), 503–517. Doi.org/10.1007/s11240-021-02142-y
Erazo-Garcia, M. P., Guadalupe, J. J., Rowntree, J. K., Borja-Serrano, P., de los Monteros-Silva, N. E., & De Lourdes Torres, M. (2021). Assessing the genetic diversity of Ilex guayusa loes., a medicinal plant from the ecuadorian amazon. Diversity, 13(5), 182. Doi.org/10.3390/D13050182/S1
Hashim, F. A., Mostafa, R. R., Hussien, A. G., Mirjalili, S., & Sallam, K. M. (2023). A physical law-based algorithm for numerical optimization. Knowledge-Based Systems, 260, 110146. Doi.org/10.1016/J.KNOSYS.2022.110146
Jha, A. K., & Sit, N. (2022). Extraction of bioactive compounds from plant materials using combination of various novel methods: A review. Trends in Food Science & Technology, 119, 579–591. Doi.org/10.1016/J.TIFS.2021.11.019
Kelebek, H., Sasmaz, H. K., Aksay, O., Selli, S., Kahraman, O., & Fields, C. (2024). Exploring the Impact of Infusion Parameters and In Vitro Digestion on the Phenolic Profile and Antioxidant Capacity of Guayusa (Ilex guayusa Loes.) Tea Using Liquid Chromatography, Diode Array Detection, and Electrospray Ionization Tandem Mass Spectrometr. Foods, 13(5), 694. Doi.org/10.3390/FOODS13050694
Korniyenko, B., & Ladieva, L. (2021). Mathematical Modeling Dynamics of the Process Dehydration and Granulation in the Fluidized Bed. Advances in Intelligent Systems and Computing, 1247, 18–30. Doi.org/10.1007/978-3-030-55506-1_2
Lalji, S. M., Ali, S. I., Ahmed, R., Hashmi, S., & Awan, Z. U. H. (2022). Comparative performance analysis of different swelling kinetic models for the evaluation of shale swelling. Journal of Petroleum Exploration and Production Technology, 12(5), 1237–1249. Doi.org/10.1007/S13202-021-01387-9/TABLES/8
Li, R., Huang, Q., Zhang, D., Zhu, X., Shan, J., & Wang, J. (2020). An aging theory-based mathematic model for estimating the wax content of wax deposits using the Fick’s second law. AIChE Journal, 66(4), e16892. Doi.org/10.1002/AIC.16892
Luna-Fox, S. B., Álvarez-Castro, R. R., Peñafiel-Bonilla, N. J., Radice, M., Scalvenzi, L., Arteaga-Crespo, Y., López-Hernández, O. D., & Bravo-Sánchez, L. R. (2023a). Elaboración de un preparado hidrosoluble en forma de sólido pulverulento a partir de Ilex guayusa Loes. La Técnica Revista de Las Agrociencias, 13(1). Doi.org/10.33936/LATECNICA.V13I1.5725
Mahoney, C. R., Giles, G. E., Marriott, B. P., Judelson, D. A., Glickman, E. L., Geiselman, P. J., & Lieberman, H. R. (2019). Intake of caffeine from all sources and reasons for use by college students. Clinical Nutrition, 38(2), 668–675. Doi.org/10.1016/J.CLNU.2018.04.004
Manzano-Santana, P., Quijano-Avilés, M., Chóez-Guaranda, I., Barragán, A., Viteri-Espinoza, R., Martínez, D., Camacho, C., & Miranda-Martínez, M. (2018). Effect of drying methods on physical and chemical properties of Ilex guayusa leaves. Revista Facultad Nacional de Agronomía Medellín, 71(3), 8617–8622. Doi.org/10.15446/RFNAM.V71N3.71667
Orji, E., Ugwu, A., Ugwuanyi, C., Cyril, M., Uwakwe, E., & Elejere, U. (2022). Reducing Errors In Slope In Physics Graphs Using Origin Lab Software. Webology, 19(3), 1-12.https://www.webology.org/data-cms/articles/20220503121303pmwebology%2019%20(3)%20-%208%20pdf.pdf
Paladines-Santacruz, G., Orellana-Manzano, A., Sarmiento, G., Pilozo, G., Iñiga, E., Zaruma-Torres, F., Ortíz-Ulloa, J., Quijano-Avilés, M., Di Grumo, D., Orellana-Manzano, S., Villacrés, M. del C., Manzano, P., & Vanden Berghe, W. (2021). Acute oral toxicity of a novel functional drink based on Ilex guayusa, Vernonanthura patens, and cocoa husk. Toxicology Reports, 8, 747–752. Doi.org/10.1016/J.TOXREP.2021.03.026
Peleg, M. (1988). An Empirical Model for the Description of Moisture Sorption Curves. Journal of Food Science, 53(4), 1216–1217. Doi.org/10.1111/J.1365-2621.1988.TB13565.X
Peñafiel-Bonilla, N. J., Luna-Fox, S. B., García-Quintana, Y., & Arteaga-Crespo, Y. (2023). Optimización de la extracción de compuestos fenólicos y actividad antioxidante en hojas de Annona muricata L. mediante la metodología de superficie de respuesta. Código Científico Revista de Investigación, 4(2), 70–87. Doi.org/10.55813/GAEA/CCRI/V4/N2/232
Rai, N., Kumari Keshri, P., Verma, A., Kamble, S. C., Mishra, P., Barik, S., Kumar Singh, S., & Gautam, V. (2021). Plant associated fungal endophytes as a source of natural bioactive compounds. Mycology, 12(3), 139–159. Doi.org/10.1080/21501203.2020.1870579
Rajput, A., Sharma, R., & Bharti, R. (2022). Pharmacological activities and toxicities of alkaloids on human health. Materials Today: Proceedings, 48, 1407–1415. Doi.org/10.1016/J.MATPR.2021.09.189
Schaefer, C., Kirk, A. T., Allers, M., & Zimmermann, S. (2020). Ion Mobility Shift of Isotopologues in a High Kinetic Energy Ion Mobility Spectrometer (HiKE-IMS) at Elevated Effective Temperatures. Journal of the American Society for Mass Spectrometry, 31(10), 2093–2101. https://pubs.acs.org/doi/abs/10.1021/jasms.0c00220
Segovia-Gómez, F., Corral, J. J., & Almajano, M. P. (2013). Estudio cinético de la extracción Sólido-Líquido de los compuestos polifenólicos del Residuo del Aguacate. JORNADES DE RECERCA EUETIB, 8(2), 131–138. https://upcommons.upc.edu/bitstream/handle/2099/14999/Estudio cinético de la extracción Sólido-Líquido de los compuestos polifenólicos del Residuo del Aguacate.pdf
Tepe, T. K. (2024). Effect of pretreatments on drying characteristics, rehydration properties, and total energy consumption of carrot slices: comparison between thin layer mathematical modelling and artificial neural network modelling. Biomass Conversion and Biorefinery, 14(1), 1373–1387. Doi.org/10.1007/S13399-023-04925-Z/METRICS
Toscano, S., Trivellini, A., Cocetta, G., Bulgari, R., Francini, A., Romano, D., & Ferrante, A. (2019). Effect of Preharvest Abiotic Stresses on the Accumulation of Bioactive Compounds in Horticultural Produce. Frontiers in Plant Science, 10, 468818. Doi.org/10.3389/FPLS.2019.01212/BIBTEX
Vandeponseele, A., Draye, M., Piot, C., & Chatel, G. (2021). Study of Influential Parameters of the Caffeine Extraction from Spent Coffee Grounds: From Brewing Coffee Method to the Waste Treatment Conditions. Clean Technologies, 3(2), 335–350. Doi.org/10.3390/CLEANTECHNOL3020019
Yu, J., Feng, Y., Sun, D., Ren, W., Shao, C., & Sun, R. (2022). Highly Conductive and Mechanically Robust Cellulose Nanocomposite Hydrogels with Antifreezing and Antidehydration Performances for Flexible Humidity Sensors. ACS Applied Materials and Interfaces, 14(8), 10886–10897. https://pubs.acs.org/doi/abs/10.1021/acsami.2c00513
Bucić-Kojić, A., Planinić, M., Tomas, S., Bilić, M., & Velić, D. (2007). Study of solid-liquid extraction kinetics of total polyphenols from grape seeds. Journal of Food Engineering, 81(1), 236–242. Doi.org/10.1016/j.jfoodeng.2006.10.027
Cadena-Carrera, S., Tramontin, D. P., Jacques, R., Scapin, E., Müller, J. M., & Hense, H. (2023). Green-based methods to obtain bioactive compounds from Ilex guayusa Loes. using polar solvent. Natural Product Research, 37(18), 3103–3108. Doi.org/10.1080/14786419.2022.2140802
Carvalho, S. D., Ortega, M., Orellana, M., Rodríguez, M., Folta, K. M., & Torres, M. de L. (2021). In vitro propagation of the Amazonian medicinal plant guayusa (Ilex guayusa) and effects of light in the growth and development of this shade tolerant plant. Plant Cell, Tissue and Organ Culture, 147(3), 503–517. Doi.org/10.1007/s11240-021-02142-y
Erazo-Garcia, M. P., Guadalupe, J. J., Rowntree, J. K., Borja-Serrano, P., de los Monteros-Silva, N. E., & De Lourdes Torres, M. (2021). Assessing the genetic diversity of Ilex guayusa loes., a medicinal plant from the ecuadorian amazon. Diversity, 13(5), 182. Doi.org/10.3390/D13050182/S1
Hashim, F. A., Mostafa, R. R., Hussien, A. G., Mirjalili, S., & Sallam, K. M. (2023). A physical law-based algorithm for numerical optimization. Knowledge-Based Systems, 260, 110146. Doi.org/10.1016/J.KNOSYS.2022.110146
Jha, A. K., & Sit, N. (2022). Extraction of bioactive compounds from plant materials using combination of various novel methods: A review. Trends in Food Science & Technology, 119, 579–591. Doi.org/10.1016/J.TIFS.2021.11.019
Kelebek, H., Sasmaz, H. K., Aksay, O., Selli, S., Kahraman, O., & Fields, C. (2024). Exploring the Impact of Infusion Parameters and In Vitro Digestion on the Phenolic Profile and Antioxidant Capacity of Guayusa (Ilex guayusa Loes.) Tea Using Liquid Chromatography, Diode Array Detection, and Electrospray Ionization Tandem Mass Spectrometr. Foods, 13(5), 694. Doi.org/10.3390/FOODS13050694
Korniyenko, B., & Ladieva, L. (2021). Mathematical Modeling Dynamics of the Process Dehydration and Granulation in the Fluidized Bed. Advances in Intelligent Systems and Computing, 1247, 18–30. Doi.org/10.1007/978-3-030-55506-1_2
Lalji, S. M., Ali, S. I., Ahmed, R., Hashmi, S., & Awan, Z. U. H. (2022). Comparative performance analysis of different swelling kinetic models for the evaluation of shale swelling. Journal of Petroleum Exploration and Production Technology, 12(5), 1237–1249. Doi.org/10.1007/S13202-021-01387-9/TABLES/8
Li, R., Huang, Q., Zhang, D., Zhu, X., Shan, J., & Wang, J. (2020). An aging theory-based mathematic model for estimating the wax content of wax deposits using the Fick’s second law. AIChE Journal, 66(4), e16892. Doi.org/10.1002/AIC.16892
Luna-Fox, S. B., Álvarez-Castro, R. R., Peñafiel-Bonilla, N. J., Radice, M., Scalvenzi, L., Arteaga-Crespo, Y., López-Hernández, O. D., & Bravo-Sánchez, L. R. (2023a). Elaboración de un preparado hidrosoluble en forma de sólido pulverulento a partir de Ilex guayusa Loes. La Técnica Revista de Las Agrociencias, 13(1). Doi.org/10.33936/LATECNICA.V13I1.5725
Mahoney, C. R., Giles, G. E., Marriott, B. P., Judelson, D. A., Glickman, E. L., Geiselman, P. J., & Lieberman, H. R. (2019). Intake of caffeine from all sources and reasons for use by college students. Clinical Nutrition, 38(2), 668–675. Doi.org/10.1016/J.CLNU.2018.04.004
Manzano-Santana, P., Quijano-Avilés, M., Chóez-Guaranda, I., Barragán, A., Viteri-Espinoza, R., Martínez, D., Camacho, C., & Miranda-Martínez, M. (2018). Effect of drying methods on physical and chemical properties of Ilex guayusa leaves. Revista Facultad Nacional de Agronomía Medellín, 71(3), 8617–8622. Doi.org/10.15446/RFNAM.V71N3.71667
Orji, E., Ugwu, A., Ugwuanyi, C., Cyril, M., Uwakwe, E., & Elejere, U. (2022). Reducing Errors In Slope In Physics Graphs Using Origin Lab Software. Webology, 19(3), 1-12.https://www.webology.org/data-cms/articles/20220503121303pmwebology%2019%20(3)%20-%208%20pdf.pdf
Paladines-Santacruz, G., Orellana-Manzano, A., Sarmiento, G., Pilozo, G., Iñiga, E., Zaruma-Torres, F., Ortíz-Ulloa, J., Quijano-Avilés, M., Di Grumo, D., Orellana-Manzano, S., Villacrés, M. del C., Manzano, P., & Vanden Berghe, W. (2021). Acute oral toxicity of a novel functional drink based on Ilex guayusa, Vernonanthura patens, and cocoa husk. Toxicology Reports, 8, 747–752. Doi.org/10.1016/J.TOXREP.2021.03.026
Peleg, M. (1988). An Empirical Model for the Description of Moisture Sorption Curves. Journal of Food Science, 53(4), 1216–1217. Doi.org/10.1111/J.1365-2621.1988.TB13565.X
Peñafiel-Bonilla, N. J., Luna-Fox, S. B., García-Quintana, Y., & Arteaga-Crespo, Y. (2023). Optimización de la extracción de compuestos fenólicos y actividad antioxidante en hojas de Annona muricata L. mediante la metodología de superficie de respuesta. Código Científico Revista de Investigación, 4(2), 70–87. Doi.org/10.55813/GAEA/CCRI/V4/N2/232
Rai, N., Kumari Keshri, P., Verma, A., Kamble, S. C., Mishra, P., Barik, S., Kumar Singh, S., & Gautam, V. (2021). Plant associated fungal endophytes as a source of natural bioactive compounds. Mycology, 12(3), 139–159. Doi.org/10.1080/21501203.2020.1870579
Rajput, A., Sharma, R., & Bharti, R. (2022). Pharmacological activities and toxicities of alkaloids on human health. Materials Today: Proceedings, 48, 1407–1415. Doi.org/10.1016/J.MATPR.2021.09.189
Schaefer, C., Kirk, A. T., Allers, M., & Zimmermann, S. (2020). Ion Mobility Shift of Isotopologues in a High Kinetic Energy Ion Mobility Spectrometer (HiKE-IMS) at Elevated Effective Temperatures. Journal of the American Society for Mass Spectrometry, 31(10), 2093–2101. https://pubs.acs.org/doi/abs/10.1021/jasms.0c00220
Segovia-Gómez, F., Corral, J. J., & Almajano, M. P. (2013). Estudio cinético de la extracción Sólido-Líquido de los compuestos polifenólicos del Residuo del Aguacate. JORNADES DE RECERCA EUETIB, 8(2), 131–138. https://upcommons.upc.edu/bitstream/handle/2099/14999/Estudio cinético de la extracción Sólido-Líquido de los compuestos polifenólicos del Residuo del Aguacate.pdf
Tepe, T. K. (2024). Effect of pretreatments on drying characteristics, rehydration properties, and total energy consumption of carrot slices: comparison between thin layer mathematical modelling and artificial neural network modelling. Biomass Conversion and Biorefinery, 14(1), 1373–1387. Doi.org/10.1007/S13399-023-04925-Z/METRICS
Toscano, S., Trivellini, A., Cocetta, G., Bulgari, R., Francini, A., Romano, D., & Ferrante, A. (2019). Effect of Preharvest Abiotic Stresses on the Accumulation of Bioactive Compounds in Horticultural Produce. Frontiers in Plant Science, 10, 468818. Doi.org/10.3389/FPLS.2019.01212/BIBTEX
Vandeponseele, A., Draye, M., Piot, C., & Chatel, G. (2021). Study of Influential Parameters of the Caffeine Extraction from Spent Coffee Grounds: From Brewing Coffee Method to the Waste Treatment Conditions. Clean Technologies, 3(2), 335–350. Doi.org/10.3390/CLEANTECHNOL3020019
Yu, J., Feng, Y., Sun, D., Ren, W., Shao, C., & Sun, R. (2022). Highly Conductive and Mechanically Robust Cellulose Nanocomposite Hydrogels with Antifreezing and Antidehydration Performances for Flexible Humidity Sensors. ACS Applied Materials and Interfaces, 14(8), 10886–10897. https://pubs.acs.org/doi/abs/10.1021/acsami.2c00513
Publicado
2024-08-16
Cómo citar
Luna-Fox, S., Uvidia-Armijo, J., & Rivera-Barreto, J. (2024). Estudio cinético de la extracción sólido-líquido de cafeína en Ilex guayusa Loes. Revista De La Facultad De Agronomía De La Universidad Del Zulia, 41(3), e244128. Recuperado a partir de http://www.produccioncientifica.luz.edu.ve/index.php/agronomia/article/view/42581
Número
Sección
Tecnología de Alimentos
Derechos de autor 2024 Sting Brayan Luna-Fox, Jhoeel Hernán Uvidia-Armijo, Jannys Lizeth Rivera-Barreto
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-CompartirIgual 4.0.
